The reaction mechanisms of 1-methylimidazole with a number of alkyl halides including ethyl chloride, butyl chloride, ethyl bromide and butyl bromide were determined using density-functional theory ( DFT). 用密度泛函理论考察了甲基咪唑和一系列的卤代烷烃(氯乙烷,氯丁烷,溴乙烷,溴丁烷)反应合成咪唑类离子液体的反应机理。
Ethyl bromide or iodide at 20 torr was irradiated by a TEA CO2 laser. The reaction products were identified by means of infrared spectrometry, gas chromatography and CW CO2 laser photoacoustic spectroscopy. ~20托溴乙烷或碘乙烷用TEACO2激光辐照,其产物用红外光谱、气相色谱和CWCO2激光光声光谱检测。
When copolymerization is carried out in ethyl bromide solution at-20 ℃ to-78 ℃, cationic and free radical mechanisms exist simultaneou-sly; by further lowering reaction temperature, cationic mechanism becomes predominant. 在溴乙烷中,-20℃到-78℃温度范围内共聚时,阳离子、自由基历程并存,并随着温度降低阳离子聚合逐渐占优势。
With ethyl alcohol as solvent and sodium iodide as catalyst, 1,4-dibutoxybenzene was synthesized from metal sodium, hydroquinone and n-butyl bromide. 以乙醇为溶剂,碘化钠为催化剂,由金属钠、对苯二酚和溴丁烷合成了1,4-二丁氧基苯。
Using one-color two-photon ( 1C2P) scheme, high-resolution mass analyzed threshold ionization MATI spectra of ethyl bromide have been recorded. 利用单色双光子(1C2P)技术得到了高精度的溴乙烷分子的质量分辨阈值(MATI)光谱,精确给出了溴乙烷分子的绝热电离势和离子振动频率。
New Process of Ethyl Bromide Synthesis with Solid Super acid Catalyst 固体酸催化合成溴乙烷新工艺
The chain conformation of Cu(ⅱ) complex of poly ( 4 vinylpyridine) partially quaternized by ethyl bromide ( EBQP4VP) in ethanol water mixture is dependent on the solvent composition. 溴乙烷部分季胺盐化聚4-乙烯基吡啶EBQB4VP-Cu(Ⅱ)络合物在乙醇-水混合溶剂中时,其链构象因溶剂组成而异。
Crosslinked poly-4-vinylpyridine quaternized with methyl iodide, ethyl bromide has been prepared and the quaternary salts have been used for the support of the Pd catalyst. 制备了交联聚4-乙烯基吡啶及碘甲烷,溴乙烷季铵化的聚4-乙烯基吡啶负载钯催化剂,考察了它们催化丙烯酸甲酯加氢反应的性能。
Mass analyzed threshold ionization spectra of ethyl bromide 溴乙烷分子的质量分辨阈值光谱